Ion exchange for nuclear waste treatment and for recycling

  • A.I. Virtasen aukio 1 (PL 55)

    00014 Helsingin yliopisto

    Finland

Publications

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2020

A simple method for quantifying iodate and iodide fractions in solution using Ag+-impregnated activated carbon

Suorsa, V., Otaki, M., Zhang, W., Virkanen, J. & Koivula, R., Apr 2020, In : Journal of Radioanalytical and Nuclear Chemistry. 324, 1, p. 135-142 8 p.

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Column Separation of Am(III) and Eu(III) by α-Zirconium Phosphate Ion Exchanger in Nitric Acid

Wiikinkoski, E. W., Rautsola, I., Xu, J. & Koivula, R., 2020, In : ChemEngineering. 4, 1, 13 p., 14.

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Determination of C-14, Fe-55, Ni-63 and gamma emitters in activated RPV steel samples: a comparison between calculations and experimental analysis

Leskinen, A., Salminen-Paatero, S., Räty, A., Tanhua-Tyrkkö, M., Iso-Markku, T. & Puukko, E., Jan 2020, In : Journal of Radioanalytical and Nuclear Chemistry. 323, 1, p. 399-413 15 p.

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Multi-site surface complexation modelling of Se(IV) sorption on biotite

Li, X., Puhakka, E., Liu, L., Zhang, W., Ikonen, J., Lindberg, A. & Siitari-Kauppi, M., 5 Feb 2020, In : Chemical Geology. 533, 11 p., 119433.

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Tandem-Mass-Tag based proteomic analysis facilitates analyzing critical factors of porous silicon nanoparticles in determining their biological responses under diseased condition

Li, Y., Liu, Z., Li, L., Lian, W., He, Y., Khalil, E., Makila, E., Zhang, W., Torrieri, G., Liu, X., Su, J., Xiu, Y., Fontana, F., Salonen, J., Hirvonen, J., Liu, W., Zhang, H., Santos, H. A. & Deng, X., 7 Aug 2020, In : Advanced Science. 7, 15, 12 p., 2001129.

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2019

A spectroscopic study of trivalent cation (Cm3+ and Eu3+) sorption on monoclinic zirconia (ZrO2)

Eibl, M., Virtanen, S., Pischel, F., Bok, F., Lönnrot, S., Shaw, S. & Huittinen, N., 1 Sep 2019, In : Applied Surface Science. 487, p. 1316-1328 13 p.

Research output: Contribution to journalArticleScientificpeer-review

Batch sorption experiments of cesium and strontium on crushed rock and biotite for the estimation of distribution coefficients on intact crystalline rock

Lehto, J., Puukko, E., Lindberg, A. & Voutilainen, M., 13 Aug 2019, In : Heliyon. 5, 8, 9 p., 02296.

Research output: Contribution to journalArticleScientificpeer-review

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Electrospun sodium titanate fibres for fast and selective water purification

Santala, E., Koivula, R., Harjula, R. & Ritala, M., 6 Dec 2019, In : Environmental Technology. 40, 27, p. 3561-3567 7 p.

Research output: Contribution to journalArticleScientificpeer-review

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Novel electroblowing synthesis of submicron zirconium dioxide fibers: effect of fiber structure on antimony(v) adsorption

Paajanen, J., Lönnrot, S., Heikkilä, M., Meinander, K., Kemell, M., Hatanpää, T., Ainassaari, K., Ritala, M. & Koivula, R., 1 Nov 2019, In : Nanoscale Advances. 1, 11, p. 4373-4383 11 p.

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Selective extraction of aliphatic amines by functionalized mesoporous silica-coated solid phase microextraction Arrow

Lan, H., Zhang, W., Smått, J-H., Koivula, R., Hartonen, K. & Riekkola, M-L., Jul 2019, In : Microchimica Acta. 186, 7, 11 p., 412.

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Selective ion-exchange separation of scandium(III) over iron(III) by crystalline alpha-zirconium phosphate platelets under acidic conditions

Avdibegović, D., Zhang, W., Xu, J., Regadío, M., Koivula, R. & Binnemans, K., 15 May 2019, In : Separation and Purification Technology. 215, p. 81-90 10 p.

Research output: Contribution to journalArticleScientificpeer-review

Solid-State Conversion of Scandium Phosphate into Scandium Oxide with Sodium Compounds

Yagmurlu, B., Zhang, W., Heikkilä, M., Koivula, R. & Friedrich, B., 14 Aug 2019, In : Industrial & Engineering Chemistry Research. 58, 32, p. 14609-14620 12 p.

Research output: Contribution to journalArticleScientificpeer-review

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2018

Electromigration experiments for studying transport parameters and sorption of cesium and strontium on intact crystalline rock

Puukko, E., Lehto, J., Lindberg, A. & Voutilainen, M., Oct 2018, In : Journal of Contaminant Hydrology. 217, p. 1-7 7 p.

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Intralanthanide Separation on Layered Titanium(IV) Organophosphate Materials via a Selective Transmetalation Process

Zhang, W., Hietala, S., Khryashchev, L., Hatanpää, T., Doshi, B. & Koivula, R., 4 Jul 2018, In : ACS Applied Materials & Interfaces. 10, 26, p. 22083-22093 11 p.

Research output: Contribution to journalArticleScientificpeer-review

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Polyacrylonitrile-encapsulated amorphous zirconium phosphate composite adsorbent for Co, Nd and Dy separations

Xu, J., Virolainen, S., Zhang, W., Kuva, J., Sainio, T. & Koivula, R., 1 Nov 2018, In : Chemical Engineering Journal. 351, p. 832-840 9 p.

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Removal of Cd2+, Ni2+ and PO43− from aqueous solution by hydroxyapatite-bentonite clay-nanocellulose composite

Hokkanen, S. R., Bhatnagar, A., Srivastava, V., Suorsa, M. V. & Sillanpää, M., 15 Oct 2018, In : International Journal of Biological Macromolecules. 118, p. 903-912 10 p.

Research output: Contribution to journalArticleScientificpeer-review

Separation of cobalt, neodymium and dysprosium using amorphous zirconium phosphate

Xu, J., Koivula, R. T., Zhang, W., Wiikinkoski, E. W., Hietala, S. & Harjula, R. O., Jan 2018, In : Hydrometallurgy. 175, p. 170-178 9 p.

Research output: Contribution to journalArticleScientificpeer-review

Sorption competition and kinetics of trivalent cations (Eu, Y and Cm) on corundum (alpha-Al2O3 ): A batch sorption and TRLFS study

Virtanen, S., Meriläinen, S., Eibl, M., Rabung, T., Lehto, J. & Huittinen, N., May 2018, In : Applied Geochemistry. 92, p. 71-81 11 p.

Research output: Contribution to journalArticleScientificpeer-review

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2017

Effects of synthesis conditions on ion exchange properties of α-zirconium phosphate for Eu and Am

Wiikinkoski, E. W., Harjula, R. O., Lehto, J. K., Kemell, M. L. & Koivula, R. T., Dec 2017, In : Radiochimica Acta. 105, 12, p. 1033–1042 10 p.

Research output: Contribution to journalArticleScientificpeer-review

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Efficient and Selective Recovery of Trace Scandium by Inorganic Titanium Phosphate Ion-Exchangers from Leachates of Waste Bauxite Residue

Zhang, W., Koivula, R., Wiikinkoski, E., Xu, J., Hietala, S., Lehto, J. & Harjula, R., 20 Feb 2017, In : ACS Sustainable Chemistry & Engineering. 5, 4, p. 3103-3114 12 p.

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HF-Free Synthesis of α-Zirconium Phosphate and Its Use as Ion Exchanger for Separation of Nd(III) and Dy(III) from a Ternary Co–Nd–Dy System

Xu, J., Wiikinkoski, E. W., Koivula, R. T., Zhang, W., Ebin, B. & Harjula, R. O., 2017, In : Journal of Sustainable Metallurgy . 3, 3, p. 646-658 13 p.

Research output: Contribution to journalArticleScientificpeer-review

Titanium Alkylphosphate Functionalised Mesoporous Silica for Enhanced Uptake of Rare-Earth Ions

Zhang, W., Avdibegovic, D., Koivula, R., Hatanpää, T., Hietala, S., Regadio, M., Binnemans, K. & Harjula, R., 7 Dec 2017, In : Journal of Materials Chemistry. A. 5, 45, p. 23805-23814 10 p.

Research output: Contribution to journalArticleScientificpeer-review

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2016

Removal of cobalt from aqueous solution containing EDTA under UV-C irradiation by antimony oxide

Malinen, L., Koivula, R. & Harjula, R., Jun 2016, In : Radiochimica Acta. 104, 6, p. 415-422 8 p.

Research output: Contribution to journalArticleScientificpeer-review

Sorption of cesium on boreal forest soil II. The effect of time, incubation conditions, pH and competing cations

Söderlund, M., Virtanen, S., Välimaa, I., Lempinen, J., Hakanen, M. & Lehto, J., Aug 2016, In : Journal of Radioanalytical and Nuclear Chemistry. 309, 2, p. 647-657 11 p.

Research output: Contribution to journalArticleScientificpeer-review

2014

GROUP SEPARATION OF HEAVY METALS FOLLOWED BY SUBSEQUENT AND INDIVIDUAL SEPARATION OF LANTHANIDES BY CHELATION CHROMATOGRAPHY

Borai, E., Ekholm, P. & Harjula, R., 2014, In : Journal of Liquid Chromatography & Related Technologies. 37, 11, p. 1614-1631 18 p.

Research output: Contribution to journalArticleScientificpeer-review

Modeling of cesium sorption on biotite using cation exchange selectivity coefficients

Kyllönen, J., Hakanen, M., Lindberg, A., Harjula, R., Vehkamaki, M. & Lehto, J., Oct 2014, In : Radiochimica Acta. 102, 10, p. 919-929 11 p.

Research output: Contribution to journalArticleScientificpeer-review

Polymer-Inorganic Coatings Containing Nanosized Sorbents Selective to Radionuclides. 2. Latex/Tin Oxide Composites for Cobalt Fixation

Bratskaya, S., Mironenko, A., Koivula, R., Synytska, A., Musyanovych, A., Simon, F., Marinin, D., Goebel, M., Harjula, R. & Avramenko, V., 2014, In : ACS Applied Materials & Interfaces. 6, 24, p. 22387-22392 6 p.

Research output: Contribution to journalArticleScientificpeer-review

Removal of Ni-63 and Co-57 from aqueous solution using antimony doped tin dioxide-polyacrylonitrile (Sb doped SnO2-PAN) composite ion-exchangers

Inan, S., Koivula, R. & Harjula, R., Jan 2014, In : Journal of Radioanalytical and Nuclear Chemistry. 299, 1, p. 901-908 8 p.

Research output: Contribution to journalArticleScientificpeer-review

2013

Effect of EDTA and some other interfering species on the adsorption of Co(II) by EDTA-modified chitosan

Repo, E., Koivula, R., Harjula, R. & Sillanpää, M., 15 Jul 2013, In : Desalination. 321, p. 93-102 10 p.

Research output: Contribution to journalArticleScientificpeer-review

Separation of Cobalt from Europium with Mesoporous Hybrid Silica-Poly(styrene) Impregnated Chelating Resin

Borai, E., Karesoja, M. & Harjula, R., 2013, In : Mineral Processing and Extractive Metallurgy Review. 34, 1, p. 57-72 16 p.

Research output: Contribution to journalArticleScientificpeer-review

Stable and selective scintillating anion-exchange sensors for quantification of 99TcO4- in natural freshwaters

Seliman, A. F., Helariutta, K., Wiktorowicz, S. J., Tenhu, H. & Harjula, R., Dec 2013, In : Journal of Environmental Radioactivity. 126, p. 156-164 9 p.

Research output: Contribution to journalArticleScientificpeer-review

2012

Ion exchange properties of sulfonated polycarbonate and polyimide track etch membranes

Koivula, R., Makkonen-Craig, S. A., Harjula, R. & Paronen, M., 2012, In : Reactive & Functional Polymers. 72, 1, p. 92-97 6 p.

Research output: Contribution to journalArticleScientificpeer-review

Separation of Europium from Cobalt Using Antimony Silicates in Sulfate Acidic Media

Borai, E., Attallah, M., Harjula, R., Koivula, R. & Paajanen, A., 17 Jan 2012, In : Mineral Processing and Extractive Metallurgy Review. 33, 3, p. 204-219 16 p.

Research output: Contribution to journalArticleScientificpeer-review

2011

Capture of Co(II) from its aqueous EDTA-chelate by DTPA-modified silica gel and chitosan.

Repo, E., Malinen, L., Koivula, R., Harjula, R. & Sillanpää, M., 2011, In : Journal of Hazardous Materials. 187, 1-3, p. 122-132 11 p.

Research output: Contribution to journalArticleScientificpeer-review

Selective Removal of Cesium Using Zirconium(IV) Tungstate as an Inorganic Ion Exchanger from Aqueous Solution

Attallah, M. F., Borai, E. E., Harjula, R., Paajanen, A. A., Karesoja, M. & Koivula, R., 25 Nov 2011, In : Journal of Materials Science and Engineering B . 1, 6B, p. 736-746

Research output: Contribution to journalArticleScientificpeer-review

Selective Sorption of Technetium on Antimony-Doped Tin Dioxide.

Koivula, R. & Harjula, R., 2011, In : Separation Science and Technology. 46, 2, p. 315-320 6 p.

Research output: Contribution to journalArticleScientificpeer-review

2010

Nanoporous manganese oxides as environmental protective materials: Effect of Ca and Mg on metals sorption

Pakarinen, J., Koivula, R., Laatikainen, M., Laatikainen, K., Paatero, E. & Harjula, R., 2010, In : Journal of Hazardous Materials. 180, 1-3, p. 234-240 7 p.

Research output: Contribution to journalArticleScientificpeer-review

Preparation of silica-supported nanoporous manganese oxides

Laatikainen, K., Pakarinen, J., Laatikainen, M., Koivula, R., Harjula, R. & Paatero, E., 2010, In : Separation and Purification Technology. 75, 3, p. 377-384 8 p.

Research output: Contribution to journalArticleScientificpeer-review

Sorption of Radiocobalt and other Activation Product Radionuclides on Titanium Oxide Material CoTreat

Harjula, R., Kelokaski, M. & Leinonen, H. T., 2010, In : Radiochimica Acta. 98, 06, p. 341-345 5 p.

Research output: Contribution to journalArticleScientificpeer-review

The effect of dopant's valence ( plus III and plus V) on the anion/cation uptake properties of antimony-doped tin dioxide

Koivula, R., 2010, In : Central European Journal of Chemistry. 8, 6, p. 1179-1184 6 p.

Research output: Contribution to journalArticleScientificpeer-review

2009

Behavior of silica-supported manganese oxides in hydrometallurgical separations

Pakarinen, J., Laatikainen, M., Sirola, K., Paatero, E., Koivula, R. & Harjula, R., 2009, In : Separation Science and Technology. 44, p. 3045-3074 30 p.

Research output: Contribution to journalArticleScientificpeer-review

Efficient removal of cesium from low-level radioactive liquid waste using natural and impregnated zeolite minerals

Borai, E. H., Harjula, R., Malinen, L. & Paajanen, A., 2009, In : Journal of Hazardous Materials. 172, p. 416-422 7 p.

Research output: Contribution to journalArticleScientificpeer-review

Removal of radiocobalt from EDTA-complexes using oxidation and selective ion exchange

Malinen, L., Koivula, R., Harjula, R. & Malinen, LE. K., 2009, In : Water Science and Technology. 60, 4, p. 1097-1101 5 p.

Research output: Contribution to journalArticleScientificpeer-review

Sorption of radiocobalt and its EDTA complex on titanium antimonates

Malinen, L., Koivula, R. & Harjula, R., 2009, In : Journal of Hazardous Materials. 172, p. 875-879 5 p.

Research output: Contribution to journalArticleScientificpeer-review

Use of hydrometallurgical wastewater as a precursor for the synthesis of cryptomelane-type manganese dioxide ion exchange material

Koivula, R., Pakarinen, J., Sivenius, M., Sirola, K., Harjula, R. & Paatero, E., 2009, In : Separation and Purification Technology. 70, p. 53-57 5 p.

Research output: Contribution to journalArticleScientificpeer-review

2008

Nanosize latexes containing polyacrylic acid and their role in transport and immobilization of radionuclides at nuclear energy objects

Avramenko, V. A., Bratskaya, S. Y., Egorin, A. M., Markovtseva, T. G., Ryabushkin, A. N. & Harjula, R., 2008, In : Voprosy Radiatsionnoi Bezopasnosti. 4, p. 23-29 7 p.

Research output: Contribution to journalArticleScientificpeer-review

2007

Novel highly selective inorganic ion exchangers for the treatment of promblematic liquid redwaste

Harjula, R., Koivula, R., Paajanen, A., Helariutta, K., Kuronen, M., Kelokaski, P. & Sarparanta, M., 2007, In : Technical document/ International Atomic Energy Agency. 1579 (2007), 14 s

Research output: Contribution to journalArticleScientificpeer-review