Multicomb polymeric supramolecules and their self-organization: Combination of coordination and ionic interactions

Sami Valkama; Olli Lehtonen; Kristian Lappalainen; Harri Kosonen; Pascal Castro; Timo Repo; Mika Torkkeli; Ritva Serimaa; Gerrit ten Brinke; Markku Leskelä; Olli Ikkala

doi:10.1002/marc.200390084

Multicomb polymeric supramolecules and their self-organization: Combination of coordination and ionic interactions

Sami Valkama, Olli Lehtonen, Kristian Lappalainen, Harri Kosonen, Pascal Castro, Timo Repo, Mika Torkkeli, Ritva Serimaa, Gerrit ten Brinke, Markku Leskelä, Olli Ikkala

Research output: Contribution to journal › Article › Scientific › peer-review

Abstract

Several alkyl side chains are bonded to each polymeric repeat unit using both coordinated ligands and electrostatically bound counterions to directly control the interface curvature of the self-organized structures. 2,6-Bis(octylaminomethyl)pyridine is Zn-coordinated to poly(4-vinylpyridine) (P4VP) with dodecylbenzensulfonate (DBS) counterions, leading to multicomb polymeric supramolecules, poly[(4VP)Zn(2,6-bis(octylaminomethyl)-pyridine)(DBS)(2)]. Coordination is evidenced by infrared spectroscopy and visualized by quantum chemical calculations. The amorphous hexagonal self-organized structures are characterized using X-ray measurements.

Original language	English
Journal	Macromolecular Rapid Communications
Volume	24
Issue number	9
Pages (from-to)	556-560
Number of pages	5
ISSN	1022-1336
DOIs	https://doi.org/10.1002/marc.200390084
Publication status	Published - 2003
MoE publication type	A1 Journal article-refereed

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10.1002/marc.200390084

Cite this

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title = "Multicomb polymeric supramolecules and their self-organization: Combination of coordination and ionic interactions",

abstract = "Several alkyl side chains are bonded to each polymeric repeat unit using both coordinated ligands and electrostatically bound counterions to directly control the interface curvature of the self-organized structures. 2,6-Bis(octylaminomethyl)pyridine is Zn-coordinated to poly(4-vinylpyridine) (P4VP) with dodecylbenzensulfonate (DBS) counterions, leading to multicomb polymeric supramolecules, poly[(4VP)Zn(2,6-bis(octylaminomethyl)-pyridine)(DBS)(2)]. Coordination is evidenced by infrared spectroscopy and visualized by quantum chemical calculations. The amorphous hexagonal self-organized structures are characterized using X-ray measurements.",

keywords = "amphiphiles, coordination, functionalized counterion, morphology, self-organization",

author = "Sami Valkama and Olli Lehtonen and Kristian Lappalainen and Harri Kosonen and Pascal Castro and Timo Repo and Mika Torkkeli and Ritva Serimaa and {ten Brinke}, Gerrit and Markku Leskel{\"a} and Olli Ikkala",

year = "2003",

doi = "10.1002/marc.200390084",

language = "English",

volume = "24",

pages = "556--560",

journal = "Macromolecular Rapid Communications",

issn = "1022-1336",

publisher = "Wiley-VCH",

number = "9",

}

TY - JOUR

T1 - Multicomb polymeric supramolecules and their self-organization: Combination of coordination and ionic interactions

AU - Valkama, Sami

AU - Lehtonen, Olli

AU - Lappalainen, Kristian

AU - Kosonen, Harri

AU - Castro, Pascal

AU - Repo, Timo

AU - Torkkeli, Mika

AU - Serimaa, Ritva

AU - ten Brinke, Gerrit

AU - Leskelä, Markku

AU - Ikkala, Olli

PY - 2003

Y1 - 2003

N2 - Several alkyl side chains are bonded to each polymeric repeat unit using both coordinated ligands and electrostatically bound counterions to directly control the interface curvature of the self-organized structures. 2,6-Bis(octylaminomethyl)pyridine is Zn-coordinated to poly(4-vinylpyridine) (P4VP) with dodecylbenzensulfonate (DBS) counterions, leading to multicomb polymeric supramolecules, poly[(4VP)Zn(2,6-bis(octylaminomethyl)-pyridine)(DBS)(2)]. Coordination is evidenced by infrared spectroscopy and visualized by quantum chemical calculations. The amorphous hexagonal self-organized structures are characterized using X-ray measurements.

AB - Several alkyl side chains are bonded to each polymeric repeat unit using both coordinated ligands and electrostatically bound counterions to directly control the interface curvature of the self-organized structures. 2,6-Bis(octylaminomethyl)pyridine is Zn-coordinated to poly(4-vinylpyridine) (P4VP) with dodecylbenzensulfonate (DBS) counterions, leading to multicomb polymeric supramolecules, poly[(4VP)Zn(2,6-bis(octylaminomethyl)-pyridine)(DBS)(2)]. Coordination is evidenced by infrared spectroscopy and visualized by quantum chemical calculations. The amorphous hexagonal self-organized structures are characterized using X-ray measurements.

KW - amphiphiles

KW - coordination

KW - functionalized counterion

KW - morphology

KW - self-organization

U2 - 10.1002/marc.200390084

DO - 10.1002/marc.200390084

M3 - Article

SN - 1022-1336

VL - 24

SP - 556

EP - 560

JO - Macromolecular Rapid Communications

JF - Macromolecular Rapid Communications

IS - 9

ER -