Redox-active organic-inorganic hybrid polyoxometalate micelles.

Katharina Kastner; Alexander J. Kibler; Erno Karjalainen; Jesum A. Fernandes; Victor Sans; Graham N. Newton

doi:10.1039/C7TA00408G

Redox-active organic-inorganic hybrid polyoxometalate micelles.

Katharina Kastner, Alexander J. Kibler, Erno Karjalainen, Jesum A. Fernandes, Victor Sans, Graham N. Newton

Research output: Contribution to journal › Article › Scientific › peer-review

Abstract

A redox-active hybrid org.-inorg. polyoxometalate surfactant showed solvent-dependent self-assembly to form nano-scale architectures. The supramol. assemblies exhibited contrasting electronic structure and redox activity to their mol. building units, and were found to be stable under electrochem. redn. and re-oxidn. [on SciFinder(R)]

Original language	English
Journal	Journal of Materials Chemistry. A
Volume	5
Issue number	23
Pages (from-to)	11577-11581
Number of pages	5
ISSN	2050-7496
DOIs	https://doi.org/10.1039/C7TA00408G
Publication status	Published - 2017
Externally published	Yes
MoE publication type	A1 Journal article-refereed

Fields of Science

NMR (phosphorus-31
redox-active org.-inorg. hybrid polyoxometalate micelles)
Cyclic voltammetry
Electrochemical oxidation
Electrochemical reduction
Hybrid organic-inorganic materials
Micelles
NMR
Particle size distribution
Self-assembly
Solvent effect
Supramolecular structure
Surfactants
Thermogravimetric analysis
UV and visible spectra (redox-active org.-inorg. hybrid polyoxometalate micelles)
Heteropoly acids Role: PEP (Physical, engineering or chemical process), PRP (Properties), PROC (Process) (redox-active org.-inorg. hybrid polyoxometalate micelles)
redox
active
org
inorg
hybrid
polyoxometalate
micelle
116 Chemical sciences

Access to Document

10.1039/C7TA00408G

Cite this

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title = "Redox-active organic-inorganic hybrid polyoxometalate micelles.",

abstract = "A redox-active hybrid org.-inorg. polyoxometalate surfactant showed solvent-dependent self-assembly to form nano-scale architectures. The supramol. assemblies exhibited contrasting electronic structure and redox activity to their mol. building units, and were found to be stable under electrochem. redn. and re-oxidn. [on SciFinder(R)]",

keywords = "NMR (phosphorus-31, redox-active org.-inorg. hybrid polyoxometalate micelles), Cyclic voltammetry, Electrochemical oxidation, Electrochemical reduction, Hybrid organic-inorganic materials, Micelles, NMR, Particle size distribution, Self-assembly, Solvent effect, Supramolecular structure, Surfactants, Thermogravimetric analysis, UV and visible spectra (redox-active org.-inorg. hybrid polyoxometalate micelles), Heteropoly acids Role: PEP (Physical, engineering or chemical process), PRP (Properties), PROC (Process) (redox-active org.-inorg. hybrid polyoxometalate micelles), redox, active, org, inorg, hybrid, polyoxometalate, micelle, 116 Chemical sciences",

author = "Katharina Kastner and Kibler, {Alexander J.} and Erno Karjalainen and Fernandes, {Jesum A.} and Victor Sans and Newton, {Graham N.}",

note = "Copyright (C) 2017 American Chemical Society (ACS). All Rights Reserved.; Section Code: 66-2; CA Section Cross-references: 72, 78; CODEN: JMCAET; CAS Registry Numbers: 2088495-37-6P Role: PEP (Physical, engineering or chemical process), PRP (Properties), SPN (Synthetic preparation), PREP (Preparation), PROC (Process) (redox-active org.-inorg. hybrid polyoxometalate micelles); 947150-46-1P; 2088495-32-1P; 2088495-33-2P; 2088495-34-3P Role: PRP (Properties), RCT (Reactant), SPN (Synthetic preparation), PREP (Preparation), RACT (Reactant or reagent) (redox-active org.-inorg. hybrid polyoxometalate micelles); 106-41-2 (4-Bromophenol); 122-52-1 (Triethylphosphite); 507-09-5 (Thioacetic acid); 2857-97-8 (Bromotrimethylsilane); 7766-50-9 (11-Bromo-1-undecene); 59111-46-5 Role: RCT (Reactant), RACT (Reactant or reagent) (redox-active org.-inorg. hybrid polyoxometalate micelles)",

year = "2017",

doi = "10.1039/C7TA00408G",

language = "English",

volume = "5",

pages = "11577--11581",

journal = "Journal of Materials Chemistry. A",

issn = "2050-7496",

publisher = "Royal Society of Chemistry",

number = "23",

}

TY - JOUR

T1 - Redox-active organic-inorganic hybrid polyoxometalate micelles.

AU - Kastner, Katharina

AU - Kibler, Alexander J.

AU - Karjalainen, Erno

AU - Fernandes, Jesum A.

AU - Sans, Victor

AU - Newton, Graham N.

N1 - Copyright (C) 2017 American Chemical Society (ACS). All Rights Reserved.; Section Code: 66-2; CA Section Cross-references: 72, 78; CODEN: JMCAET; CAS Registry Numbers: 2088495-37-6P Role: PEP (Physical, engineering or chemical process), PRP (Properties), SPN (Synthetic preparation), PREP (Preparation), PROC (Process) (redox-active org.-inorg. hybrid polyoxometalate micelles); 947150-46-1P; 2088495-32-1P; 2088495-33-2P; 2088495-34-3P Role: PRP (Properties), RCT (Reactant), SPN (Synthetic preparation), PREP (Preparation), RACT (Reactant or reagent) (redox-active org.-inorg. hybrid polyoxometalate micelles); 106-41-2 (4-Bromophenol); 122-52-1 (Triethylphosphite); 507-09-5 (Thioacetic acid); 2857-97-8 (Bromotrimethylsilane); 7766-50-9 (11-Bromo-1-undecene); 59111-46-5 Role: RCT (Reactant), RACT (Reactant or reagent) (redox-active org.-inorg. hybrid polyoxometalate micelles)

PY - 2017

Y1 - 2017

N2 - A redox-active hybrid org.-inorg. polyoxometalate surfactant showed solvent-dependent self-assembly to form nano-scale architectures. The supramol. assemblies exhibited contrasting electronic structure and redox activity to their mol. building units, and were found to be stable under electrochem. redn. and re-oxidn. [on SciFinder(R)]

AB - A redox-active hybrid org.-inorg. polyoxometalate surfactant showed solvent-dependent self-assembly to form nano-scale architectures. The supramol. assemblies exhibited contrasting electronic structure and redox activity to their mol. building units, and were found to be stable under electrochem. redn. and re-oxidn. [on SciFinder(R)]

KW - NMR (phosphorus-31

KW - redox-active org.-inorg. hybrid polyoxometalate micelles)

KW - Cyclic voltammetry

KW - Electrochemical oxidation

KW - Electrochemical reduction

KW - Hybrid organic-inorganic materials

KW - Micelles

KW - NMR

KW - Particle size distribution

KW - Self-assembly

KW - Solvent effect

KW - Supramolecular structure

KW - Surfactants

KW - Thermogravimetric analysis

KW - UV and visible spectra (redox-active org.-inorg. hybrid polyoxometalate micelles)

KW - Heteropoly acids Role: PEP (Physical, engineering or chemical process), PRP (Properties), PROC (Process) (redox-active org.-inorg. hybrid polyoxometalate micelles)

KW - redox

KW - active

KW - org

KW - inorg

KW - hybrid

KW - polyoxometalate

KW - micelle

KW - 116 Chemical sciences

U2 - 10.1039/C7TA00408G

DO - 10.1039/C7TA00408G

M3 - Article

SN - 2050-7496

VL - 5

SP - 11577

EP - 11581

JO - Journal of Materials Chemistry. A

JF - Journal of Materials Chemistry. A

IS - 23

ER -