Copolymers of 1-vinylimidazole and (meth)acrylic acid: Synthesis and polyelectrolyte properties

V.V. Annenkov, E.N. Danilovtseva, H. Tenhu, V. Aseyev, S.-P. Hirvonen, A.I. Mikhaleva

Forskningsoutput: TidskriftsbidragArtikelVetenskapligPeer review

Sammanfattning

New hydrophilic polyampholytes have been synthesized by copolymn. of 1-vinylimidazole with sodium salts of acrylic and methacrylic acids. Copolymn. reactivity ratios of the monomers are equal to: 0.54 ± 0.06 and 1.3 ± 0.3 for 1-vinylimidazole-sodium acrylate, 0.23 ± 0.01 and 2.6 ± 0.2 for 1-vinylimidazole-sodium methacrylate systems, correspondingly. Isoelec. point of the copolymers changes continuously from 2.8 to 6.7 with increasing the 1-vinylimidazole content in contrast to polyampholytes with amino instead of imidazole side groups, whose isoelec. point changes discontinuously with changing compn. Static and dynamic light scattering data point to tendency of polyampholyte macromols. to aggregation, even at pH values far from isoelec. point. [on SciFinder(R)]
Bidragets titel på inmatningsspråkCopolymers of 1-vinylimidazole and (meth)acrylic acid: Synthesis and polyelectrolyte properties.
Originalspråkengelska
TidskriftEuropean Polymer Journal
Volym40
Utgåva6
Sidor (från-till)1027-1032
Antal sidor6
ISSN0014-3057
DOI
StatusPublicerad - 2004
MoE-publikationstypA1 Tidskriftsartikel-refererad

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