Green and Fast Synthesis of 2-Arylidene-indan-1, 3-diones Using a Task-Specific Ionic Liquid

Abdolhamid  Alizadeh; Zahra  Beiranvand; Zahra Safaei; Mohammad M   Khodaei; Eveliina Repo

doi:10.1021/acsomega.0c03645

Green and Fast Synthesis of 2-Arylidene-indan-1, 3-diones Using a Task-Specific Ionic Liquid

Abdolhamid Alizadeh, Zahra Beiranvand, Zahra Safaei, Mohammad M Khodaei , Eveliina Repo

Forskningsoutput: Tidskriftsbidrag › Artikel › Vetenskaplig › Peer review

Sammanfattning

A novel method for condensation reaction of indan-1,3-dione with various aldehydes which are efficiently catalyzed by a task-specific ionic liquid, 2-hydroxyethylammonium formate, to provide the corresponding 2-arylidenindane-1,3-diones has been developed. This green, low-cost, high-yield, and fast reaction takes place at room temperature without the use of any solvent and catalyst. A plausible reaction mechanism that involves ionic liquid-assisted activation is also discussed. This work is the first report of ionic liquids as a reaction medium and catalyst for the synthesis of 2-arylidenindane-1,3-diones.

Originalspråk	engelska
Tidskrift	ACS Omega
Volym	5
Nummer	44
Sidor (från-till)	28632-28636
ISSN	2470-1343
DOI	https://doi.org/10.1021/acsomega.0c03645
Status	Publicerad - 27 okt. 2020
Externt publicerad	Ja
MoE-publikationstyp	A1 Tidskriftsartikel-refererad

Vetenskapsgrenar

416 Livsmedelsvetenskap

Åtkomst av dokument

10.1021/acsomega.0c03645Licens: CC BY-NC-ND

acsomega.0c03645Slutlig publicerad version, 831 KBLicens: CC BY-NC-ND

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title = "Green and Fast Synthesis of 2-Arylidene-indan-1, 3-diones Using a Task-Specific Ionic Liquid",

abstract = "A novel method for condensation reaction of indan-1,3-dione with various aldehydes which are efficiently catalyzed by a task-specific ionic liquid, 2-hydroxyethylammonium formate, to provide the corresponding 2-arylidenindane-1,3-diones has been developed. This green, low-cost, high-yield, and fast reaction takes place at room temperature without the use of any solvent and catalyst. A plausible reaction mechanism that involves ionic liquid-assisted activation is also discussed. This work is the first report of ionic liquids as a reaction medium and catalyst for the synthesis of 2-arylidenindane-1,3-diones.",

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author = "Abdolhamid Alizadeh and Zahra Beiranvand and Zahra Safaei and Khodaei, {Mohammad M} and Eveliina Repo",

year = "2020",

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T1 - Green and Fast Synthesis of 2-Arylidene-indan-1, 3-diones Using a Task-Specific Ionic Liquid

AU - Alizadeh, Abdolhamid

AU - Beiranvand, Zahra

AU - Safaei, Zahra

AU - Khodaei , Mohammad M

AU - Repo, Eveliina

PY - 2020/10/27

Y1 - 2020/10/27

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AB - A novel method for condensation reaction of indan-1,3-dione with various aldehydes which are efficiently catalyzed by a task-specific ionic liquid, 2-hydroxyethylammonium formate, to provide the corresponding 2-arylidenindane-1,3-diones has been developed. This green, low-cost, high-yield, and fast reaction takes place at room temperature without the use of any solvent and catalyst. A plausible reaction mechanism that involves ionic liquid-assisted activation is also discussed. This work is the first report of ionic liquids as a reaction medium and catalyst for the synthesis of 2-arylidenindane-1,3-diones.

KW - 416 Food Science

U2 - 10.1021/acsomega.0c03645

DO - 10.1021/acsomega.0c03645

M3 - Article

SN - 2470-1343

VL - 5

SP - 28632

EP - 28636

JO - ACS Omega

JF - ACS Omega

IS - 44

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